- Brajrajnagar College Library (known as B.C.Naik Library) was established in 1980, after two years of inception of the college in 1978. Since Brajrajnagar College provides teaching in +2 streams (Arts, Science and Commerce) and +3 (Arts, Science and Commerce) in Honours, Pas and Electives in History, Pol. Sc. Economics, English, Odia, Education in Arts faculty; Botany, Zoology, Chemistry, Physics an Mathematics in Science faculty and Accountancy Honours in commerce faculty, the college has equipped the library with reference books, course books, journals related to the honours subjects.
- The books those are available in the college library in different subjects as mentioned above have been bought from time to time in different academic sessions from two heads: College Library Fund and UGC Fund.
- In +2 steams the B.C.Naik Library has 2583 nos. of books. In +3 streams there are 4017 nos, of books purchased from college library fund. And 5536 nos. of books purchased from UGC fund till date. The students are conscious of using the books in Reading Room and the books are also issued to the students as per the schedule fixed for the purpose.